By Alaa S. Abd-El-Aziz, Charles E. Carraher, Pierre D. Harvey, Charles U. Pittman, Martel Zeldin
Steel- and metalloid-containing macromolecules are outlined as huge molecules (i.e., polymers, DNA, proteins) that include a steel or metalloid staff affiliated with the molecule. This quantity describes what's attainable with metal-containing polymers the place the steel is a vital aspect in acquiring wanted optical and digital houses. overlaying functions in nonlinear optical fabrics, sunlight cells, light-emitting diodes, photovoltaic cells, field-effect transistors, chemosensing units, and biosensing units, this indispensible advisor specializes in the photochemistry and photophysics of metal-containing polymers, with chapters through top participants to the middle advances during this field.Content:
Chapter 1 advent to Photophysics and Photochemistry (pages 1–43): Shawkat M. Aly, Charles E. Carraher and Pierre D. Harvey
Chapter 2 Luminescent Organometallic Coordination Polymers outfitted on Isocyanide Bridging Ligands (pages 45–87): Pierre D. Harvey, Sebastien Clement, Michael Knorr and Jerome Husson
Chapter three Luminescent Oligomeric and Polymeric Copper Coordination Compounds Assembled by means of Thioether Ligands (pages 89–158): Michael Knorr and Fabrice Guyon
Chapter four purposes of steel Containing Polymers in natural sunlight Cells (pages 159–189): Chris S. okay. Mak and Wai relations Chan
Chapter five sensible Silole?Containing Polymers (pages 191–204): Junwu Chen, Yong Cao and Ben Zhong Tang
Chapter 6 Photophysics and Photochemistry of Polysilanes for digital functions (pages 205–254): Starr Dostie, Cetin Aktik and Mihai Scarlete
Chapter 7 Polymers with Metal?Metal Bonds as versions in Mechanistic stories of Polymer Photodegradation (pages 255–287): David R. Tyler, Bevin C. Daglen and Ginger V. Shultz
Chapter eight Optical houses and Photophysics of Platinum?Containing Poly(aryleneethynylene)s (pages 289–324): Wai?Yeung Wong
Chapter nine Luminescence in Polymetallic Gold?Heteronuclear Derivatives (pages 325–364): Antonio Laguna and Jose M. Lopez?de?Luzuriaga
Chapter 10 useful Self?Assembled Zinc(II) Coordination Polymers (pages 365–385): Chi?Chung Kwok and Chi?Ming Che
Chapter eleven Redox and picture features of steel complicated Oligomer and Polymer Wires at the Electrode (pages 387–414): Mariko Miyachi and Hiroshi Nishihara
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Additional info for Macromolecules Containing Metal and Metal-Like Elements: Photophysics and Photochemistry of Metal-Containing Polymers, Volume 10
110, 310 (2006). References 43 79. J. Poulin, C. Stern, R. Guilard, P. D. Harvey, Photochem. , 82, 171 (2006). 80. K. Kilsa, J. Kajanus, J. Martensso, B. Albinsson, J. Phys. Chem. , 103, 7329 (1999). 81. J. Andreasson, J. Kajanus, J. Martensson, B. Albinsson, J. Am. Chem. , 122, 9844 (2000). 82. J. Andreasson, A. Kyrychenki, J. Martensson, B. Albinsson, Photochem. Photobiol. , 1, 111 (2002). CHAPTER 2 Luminescent Organometallic Coordination Polymers Built on Isocyanide Bridging Ligands Pierre D.
Holten, D. Bocian, J. Lindsey, Acc. Chem. , 35, 57 (2002). 65. (a) S. L. James, Coord. , 276, 32 (2003). (b) T. Tanase, Bull. Chem. Soc. , 75, 1407 (2002). 66. (a) J. M. Tour, Acc. Chem. , 33, 791 (2000). (b) R. W. Wagner, J. S. Lindsey, J. Am. Chem. , 116, 9759 (1994). 67. (a) R. W. Wagner, J. S. Lindsey, J. Seth, V. Palaniappan, D. J. Bocia, J. Am. Chem. , 118, 3996 (1996). (b) A. P. Silva, I. Dioxon, H. Gunaratne, T. Gunnlaughsson, P. Maxwell, T. E. Rice, J. Am. Chem. , 121, 1393 (1999). 68.
Second-order NLO behavior includes second harmonic generation of light that involves the frequency doubling of the incident light. Frequency mixing where the frequency of two light beams are either added or subtracted. Electrooptic eﬀects can occur where both frequency and amplitude changes and where rotation of polarization occurs. NOL behavior has been found in inorganic and organic compounds and in polymers. The structural requirement is the absence of an inversion center requiring the presence of asymmetric centers and/or poling.