By George A. Olah, G. K. Surya Prakash, Jean Sommer, Arpad Molnar
The chemistry of superacids has constructed within the final twenty years right into a box of growing to be curiosity and value. Now to be had in a brand new accelerated moment variation, this definitive paintings on superacids deals a complete evaluate of superacids and discusses the improvement of recent superacid structures and purposes of superacids within the advertising of bizarre reactions. masking Bronsted and Leurs superacids, sturdy superacids, carbocations, heterocations, and catalyzed reactions, this well timed quantity is valuable to pros, school, and graduate scholars in natural, inorganic, and actual chemistry.
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Many of the perfluoroalkanesulfonic acids have been prepared by the electrochemical fluorination reaction 20 (or conversion of the corresponding perfluoroalkane iodides to their sulfonyl halides). 27 Because of toxicity problems perfluorooctanesulfonic acid is phased out, however, from Teflon manufacturing process. Extreme care should be taken while handling the perfluoroalkanesulfonic acids. Studies suggest that extreme irritation and permanent eye damage could occur following eye contact, even if the eyes are flushed immediately with water.
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